Plasmonic‐Enhanced NIR‐II Downconversion Fluorescence beyond 1500 nm from Core–Shell–Shell Lanthanide Nanoparticles
نویسندگان
چکیده
This paper reports on the light amplification of NaGdF4:Yb,Er,[email protected]4:Yb,[email protected]4 core–shell–shell downconversion nanoparticles (CSS-DCNPs) in near-infrared second biological window (NIR-II: 1000–1700 nm) by plasmonic nanostructures. Through a precisely controlled metallic nanostructure, fluorescence from Yb3+ induced 1000 nm emission, Nd3+ 1060 and Er3+ 1527 emission are enhanced 1.6-fold, 1.7-fold, 2.2-fold, respectively, under an 808 laser excitation for CSS-DCNPs coupled with gold hole-cap nanoarray (Au-HCNA), while 980 is up to 6-fold. To gain insight into enhancement mechanism, modulation NIR-II at 1550 studied FDTD simulation lifetime measurements, showing observed can be attributed combination increased radiative decay rate.
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ژورنال
عنوان ژورنال: Advanced Optical Materials
سال: 2023
ISSN: ['2195-1071']
DOI: https://doi.org/10.1002/adom.202300477